ASYMMETRIC HYDROGENATION OF α-ACYLAMINOACRYLIC ACIDS AND ESTERS WITH AXIALLY DISSYMMETRIC BISAMINOPHOSPHINE–RHODIUM COMPLEXES
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چکیده
منابع مشابه
Asymmetric Michael addition of α-fluoro-α-nitro esters to nitroolefins: towards synthesis of α-fluoro-α-substituted amino acids.
α-Fluoro-α-nitro esters were used as reaction partners in Michael addition to nitroalkenes, and the products were obtained in excellent chemical yields and with high enantioselectivities. Moreover, α-fluoro-α-amino ester with a quaternary α-carbon was prepared for the first time.
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1980
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1980.729